Esterification (shown below) is a reaction converting a carboxylic acid to its ester. It involves only the carbonyl carbon. Esterification of $(-)$ lactic acid with methanol yields $(+)$ methyl lactate. Assuming that there are no side reactions,what is true about this reaction?

  • A
    An $S_N2$ process has occurred,inverting the absolute configuration of the chiral center
  • B
    An $S_N1$ reaction at the chiral center has inverted the optical rotation
  • C
    $A$ diastereomer has been produced; diastereomers have different physical properties including optical rotation
  • D
    Optical rotation is not directly related to absolute configuration,so the change in sign of rotation is merely a coincidence

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What is the major product of the above Friedel-Crafts reaction?

Product $(X)$ is

The final product $[D]$ of the reaction is
$CHCl_3$ $\xrightarrow[hv]{O_2} [A]$ $\xrightarrow{EtOH} [B]$ $\xrightarrow{2 \ mole \ MeMgBr} [C]$ $\xrightarrow{CaOCl_2} [D]$ $\xrightarrow{\Delta} CH_3-C(=O)-CH_3$

Identify the product $Y$ in the following reaction sequence:
$Benzene + CH_3CH_2CH_2Cl$ $\xrightarrow{AlCl_3} X$ $\xrightarrow{KMnO_4} Y$

Product $(A)$ of the reaction is:

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